ITMA David!
The crt and metalwork can become magnetised,and effect the picture purity.The tv has an automatic demagnetising circuit that works when you switch on the tv.It's quite common for this circuit to fail,causing the symptoms you are seeing.
It's not the crt itself,but you need to get it sorted.Its quite simple,the bits n bobs cost less than a tenner,but you need an Engineer to do it.
Regards,
Nick