As far as I know - no
One reason for "Radio" beeing the default source from standby is simple:
Radio is always available - e.g. CD-tray might be empty, computer switched of, ...
If BM5 is the sole audiomaster of your Link-System you can allocate "Radio" to start "Netradio" .
Manually starting the BLb3500 from Sys-Stanby sends the commannd "Radio" and the BM5 "translates" it to start "N.Radio"